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- Liberal arts and basic science courses
- Academic unit or major
- Undergraduate major in Chemical Science and Engineering
- Instructor(s)
- Tanaka Ken
- Class Format
- Lecture (Face-to-face)
- Media-enhanced courses
- Day/Period(Room No.)
- Tue3-4(M-103(H114))
- Group
- -
- Course number
- CAP.O301
- Credits
- 1
- Academic year
- 2024
- Offered quarter
- 1Q
- Syllabus updated
- 2024/3/14
- Lecture notes updated
- -
- Language used
- Japanese
- Access Index
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Course description and aims
[Lecture outline] In this course, carbonyl alpha-substitution and carbonyl condensation which are quite important for the construction of complex molecular skeletons will be explained. Also amines and heterocyclic compounds will be explained to understand the particular properties of heteroatom-containing compounds. Furthermore, pericyclic reactions are discussed.
[Aim of the course] Property of the alpha-positioned hydrogen plays an important role in the construction of complex molecular structures. In this course, students learn the character and reaction mechanisms of enols and enolate ions, and acquire the ability to design carbon-carbon bond formations. Also students understand amines and heterocyclic structures that are contained in many useful compounds. Furthermore, students can explain reactions controlled by molecular orbitals.
Student learning outcomes
By the end of this course, students acquire the following ability:
(1) Explain the formation and properties of enols and enolate ions.
(2) Explain carbonyl condensation, and suggest plans to synthesize the desired compounds.
(3) Explain the properties of amines, and utilize for various reactions.
(4) Explain the structure and properties of heterocyclic compounds, and explain the synthesis and reactions.
(5) Explain reactions with molecular orbitals.
Keywords
carbonyl condensation reactions, enolate reactions, amines, heterocyclic compounds, pericyclic reactions, organic synthesis
Competencies that will be developed
| ✔ Specialist skills | Intercultural skills | Communication skills | Critical thinking skills | ✔ Practical and/or problem-solving skills |
Class flow
This course will proceed in the following order: (1) carbonyl condensation reactions, (2) enolate reactions, (3) properties and synthesis of amines, (4) amine reactions, (5) pericyclic reactions-1, (6) pericyclic reactions-2. Then, in the final session, exercises and explanations will be given to confirm the level of understanding.
Course schedule/Required learning
| Course schedule | Required learning | |
|---|---|---|
| Class 1 | carbonyl condensation reaction | Explain carbonyl condensation reactions. |
| Class 2 | enolate reactions | Explain enolate reactions. |
| Class 3 | properties and synthesis of amines | Explain properties and synthesis of amines. |
| Class 4 | amine reactions | Explain amine reactions. |
| Class 5 | pericyclic reactions-1 | Explain pericyclic reactions-1. |
| Class 6 | pericyclic reactions-2 | Explain pericyclic reactions-2. |
| Class 7 | Practice problems and interpretation for confirming the level of understanding. | Solve practice problems by accurate understanding of the above lectures. |
Out-of-Class Study Time (Preparation and Review)
To enhance effective learning, students are encouraged to spend approximately 100 minutes preparing for class and another 100 minutes reviewing class content afterwards (including assignments) for each class.
They should do so by referring to textbooks and other course material.
Textbook(s)
McMurry Organic Chemistry
Reference books, course materials, etc.
Study Guide with Student Solutions Manual for McMurry's Organic Chemistry
Assessment criteria and methods
Practice problems and interpretation for confirming the level of understanding (90%), level of class participation (10%) (The level of class participation will be calculated by discussion, small examination and so on in the lecture.)
Related courses
- CAP.B211 ： Organic Chemistry I (Alkanes) (Chemical Science and Engineering)
- CAP.B212 ： Organic Chemistry II (Alkenes)
- CAP.B213 ： Organic Chemistry III (Aromatic Compounds)
- CAP.B214 ： Organic Chemistry IV (Nucleophilic Substitution)
Prerequisites (i.e., required knowledge, skills, courses, etc.)
The condition of the study will not be made, but it is desirable to study Organic Chemistry I (Chemical Science and Engineering), Organic Chemistry II, Organic Chemistry III, and Organic Chemistry IV.
