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- 工学院，物質理工学院，環境・社会理工学院共通科目
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- First-Year Courses
- School of Science
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School of Environment and Society
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- Graduate major in Technology and Innovation Management
- Common courses
- Liberal arts and basic science courses
- Academic unit or major
- Graduate major in Chemistry
- Instructor(s)
- Yamashita Makoto
- Class Format
- Lecture
- Media-enhanced courses
- Day/Period(Room No.)
- -
- Group
- -
- Course number
- CHM.D433
- Credits
- 2
- Academic year
- 2024
- Offered quarter
- 3Q
- Syllabus updated
- 2024/3/14
- Lecture notes updated
- -
- Language used
- English
- Access Index
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Course description and aims
Fundamental aspects of organometallic compounds will be described first, and then application to synthetic organic reactions using these organometallic compounds will be presented. Initially, synthesis and reaction of main group organometallic compounds will be discussed. Then fundamental aspects of transition metal complexes on structure, oxidation state and ligands will be discussed. Then basic reactions of transition metal compounds will be shown, and application to various kinds of synthetic reactions such as coupling reaction, metathesis reaction, etc. will be presented. Students can obtain basic knowledge of organic reactions mediated or catalyzed by organometallic complexes.
Student learning outcomes
Understanding the structures, properties, and catalytic functions of organometallic compounds, and gaining the ability to make a research proposal by utilizing the knowledge obtained in this course
Keywords
Organometallic compound, Organic syntheis,
Competencies that will be developed
| ✔ Specialist skills | Intercultural skills | Communication skills | Critical thinking skills | Practical and/or problem-solving skills |
Class flow
Lectures will be based on the distributed handouts and their explanation with writing on them. At the end of the class, students have to solve problem sets related to the lecture.
Course schedule/Required learning
| Course schedule | Required learning | |
|---|---|---|
| Class 1 | Synthesis and reaction of organolithium and magnesium compounds | Exercise problems might be given in this class. |
| Class 2 | Synthesis and reaction of group 12 metal compounds | Exercise problems might be given in this class. |
| Class 3 | Synthesis and reaction of group 13 metal compounds | Exercise problems might be given in this class. |
| Class 4 | Synthesis and reaction of group 14 metal compounds | Exercise problems might be given in this class. |
| Class 5 | Fundamental aspect of organotransition metal complexes 1 (structure, oxidation state, ligand) | Exercise problems might be given in this class. |
| Class 6 | Fundamental aspect of organotransition metal complexes 2 (elementary reactions) | Exercise problems might be given in this class. |
| Class 7 | Reaction of alkene-coordinated transition metal complexes | Exercise problems might be given in this class. |
| Class 8 | Reaction of alkyne, diene, and arene-coordinated transition metal complexes | Exercise problems might be given in this class. |
| Class 9 | Reaction of allylmetal complexes | Exercise problems might be given in this class. |
| Class 10 | Reaction of organocopper complexes | Exercise problems might be given in this class. |
| Class 11 | Cross coupling reactions 1 | Exercise problems might be given in this class. |
| Class 12 | Cross coupling reactions 2 | Exercise problems might be given in this class. |
| Class 13 | Reaction of metal hydride complexes | Exercise problems might be given in this class. |
| Class 14 | Reaction of metal carbene complexes | Exercise problems might be given in this class. |
Out-of-Class Study Time (Preparation and Review)
To enhance effective learning, students are encouraged to spend approximately 100 minutes preparing for class and another 100 minutes reviewing class content afterwards (including assignments) for each class.
They should do so by referring to textbooks and other course material.
Textbook(s)
None
Lecture handout will be uploaded via T2SCHOLA.
Reference books, course materials, etc.
Hartwig: Organotransition Metal Chemistry: From Bonding to Catalysis (Univ Science Books)
Assessment criteria and methods
Exercise problems, report, and final exam. Students' knowledge of organotransition metal chemistry along with its application to synthetic organic reactions, and their ability to apply them to problems will be assessed.
Related courses
- CHM.D401 ： Basic Concepts of Organic Chemistry I
- CHM.D402 ： Basic Concepts of Organic Chemistry II
Prerequisites (i.e., required knowledge, skills, courses, etc.)
Expected to have basic knowledge of organic chemistry.
