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- 工学院，物質理工学院，環境・社会理工学院共通科目
- Liberal arts and basic science courses
- First-Year Courses
- School of Science
- School of Engineering
- School of Materials and Chemical Technology
- School of Computing
- School of Life Science and Technology
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School of Environment and Society
- Department of Architecture and Building Engineering
- Department of Civil and Environmental Engineering
- Department of Transdisciplinary Science and Engineering
- Department of Social and Human Sciences
- Department of Innovation Science
- Graduate major in Technology and Innovation Management
- Common courses
- Liberal arts and basic science courses
- Academic unit or major
- Undergraduate major in Chemical Science and Engineering
- Instructor(s)
- Yamanaka Ichiro
- Class Format
- Lecture
- Media-enhanced courses
- Day/Period(Room No.)
- Fri3-4(W631)
- Group
- A
- Course number
- CAP.B218
- Credits
- 1
- Academic year
- 2021
- Offered quarter
- 3Q
- Syllabus updated
- 2021/5/10
- Lecture notes updated
- -
- Language used
- Japanese
- Access Index
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Course description and aims
[Summary of the course] In this course, theory and method of mathematical calculation of reaction rate for quantitative evaluation of chemical reaction will be explained., Furthermore, elucidation of reaction rate derived from reaction mechanism will be also explained.
[Aim of the course] To correctly understand chemical reactions, both thermodynamics and reaction kinetics are necessary. In this lecture, students acquire the ability to speculate reaction mechanism by comparison between a rate equation deduced from experimental results and a rate equation derived from rational reaction mechanism.
Student learning outcomes
By the end of this course, students acquire the following abilities:
(1) Ability to explain methods of measurement of reaction rate and mathematical description of reaction rate.
(2) Ability to derive rate equation from reaction mechanism.
(3) Ability to explain rate-determining step and activation energy.
(4) Ability to explain rate of reaction on solid surface.
Keywords
Reaction rate, rate-determining step, activation energy, steady state approximation, adsorption
Competencies that will be developed
| ✔ Specialist skills | Intercultural skills | Communication skills | Critical thinking skills | Practical and/or problem-solving skills |
Class flow
This course will proceed in the following order: (1) fundamentals of reaction kinetics, (2) reaction rates of complicated reactions, (3) reaction on solid surface. In the last day, practice problems and interpretation of them will be carried out to confirm the level of understanding.
Course schedule/Required learning
| Course schedule | Required learning | |
|---|---|---|
| Class 1 | Definition of reaction rate and differential rate equation | Explain definition of reaction rate and differential rate equation. |
| Class 2 | Integrated rate equation | Explain integrated rate equation. |
| Class 3 | Rate constant and activation energy | Explain rate constant and activation energy. |
| Class 4 | Elemental reaction, rate-determining step and steady state approximation | Explain elemental reaction, rate-determining step and steady state approximation |
| Class 5 | Reaction rate equations of polymerization | Derive reaction rate equations of polymerization. |
| Class 6 | Reaction rate equations of photoreaction and enzyme reaction | Derive reaction rate equations of photoreaction and enzyme reaction |
| Class 7 | Adsorption and rate equation of reaction on solid surface | Derive adsorption isotherm and reaction rate equation on solid surface |
| Class 8 | Practice problems and interpretation for confirming the level of understanding | Solve practice problems by accurate understanding of the above all lectures |
Out-of-Class Study Time (Preparation and Review)
To enhance effective learning, students are encouraged to spend approximately 100 minutes preparing for class and another 100 minutes reviewing class content afterwards (including assignments) for each class.
They should do so by referring to textbooks and other course material.
Textbook(s)
P. Atkins, J. de Paula, "Physical Chemistry", 10th Ed., Oxford University Press; ISBN-13: 978-0199697403
Reference books, course materials, etc.
None required
Assessment criteria and methods
Term-end examination (85%), level of class participation (15%) (The level of class participation will be calculated by small examination and so on in the lecture.)
Related courses
- CAP.B216 ： Physical Chemistry I (Thermodynamics)
- CAP.B217 ： Physical Chemistry II (Chemical Equilibrium)
- CAP.B219 ： Physical Chemistry (Kinetic Theory of Molecules)
Prerequisites (i.e., required knowledge, skills, courses, etc.)
The condition of the study will not be made, but it is desirable to study LAS.C107 ： Basic Chemical Thermodynamics, CAP.B216 ： Physical Chemistry I (Thermodynamics), CAP.B217 ： Physical Chemistry II (Chemical Equilibrium).
