[Summary of the lecture] In this lecture, basic electrochemistry will be explained based on two chemical rules, (i) thermodynamics: chemical potential, electrochemical potential and electrode potential and (ii) kinetics: rate of electron transfer reaction, current, diffusion process.
[Aim of the lecture] The aims are to understand basic electrochemical knowledge for electrochemical experiments by studying static and dynamic electrochemistry and essential electrochemical instruments and materials.
By the end of this course, students acquire the following ability:
(1) Ability to understand basic electrochemistry theory and experimental procedure.
(2) Ability to understand electrochemical potential, Nernst equation, inner potential, external potential, terminal voltage.
(3) Ability to understand Butler-Volmer equation, current and reaction rate, diffusion equation and current.
(4) Ability to apply electrochemistry to various scientific fields, solid chemistry, metal complex, catalysis, organic synthesis, energy conversion.
electrochemical potential, Nernst equation, inner potential, external potential, terminal voltage, Butler-Volmer equation, current and reaction rate, diffusion equation
|✔ Specialist skills||Intercultural skills||Communication skills||Critical thinking skills||Practical and/or problem-solving skills|
This lecture will proceed in the following order: (1) rule of electrochemistry and thermodynamics, (2) rule of electrochemical potential and chemical potential, (3) rule of potential and voltage, (4) rule of current and reaction rate, (5) electrochemical experiment procedures.
In the last lecture, practice problems and interpretation of them will be carried out to confirm the level of understanding.
|Course schedule||Required learning|
|Class 1||Energy and electrochemistry||Explain relation of energy to electrochemistry.|
|Class 2||Electrochemistry and thermodynamics||Explain relation of electrochemistry to thermodynamics.|
|Class 3||Electrochemical potential and chemical potential||Explain relation of electrochemical potential to chemical potential.|
|Class 4||Electrode potential and terminal voltage||Explain relation of electrode potential to terminal voltage.|
|Class 5||Current and reaction rate||Explain relation of current to reaction rate.|
|Class 6||Current and diffusion process||Explain relation of current to diffusion process.|
|Class 7||Electrochemical experiment procedures||Explain electrochemical experiment procedures.|
Electrochemistry, Hamann, Carl H. / Hamnett, Andrew / Vielstich, Wolf, completely revised and updated Edition - February 2007, ISBN 978-3-527-31069-2 - Wiley-VCH, Weinheim
Practice problems for confirming the level of understanding (85%), level of lecture participation (15%) which decided
by brief problems and discussion in every lectures.
The condition of the study will not be made, but it is desirable to study Physical Chemistry II (Chemical thermodynamics) and Physical Chemistry III (Kinetics) for well understanding.
yamanaka.i.aa[at]m.titech.ac.jp (Ichiro Yamanaka)
Make a reservation by e-mail in advance.