2019 | Physical Chemistry (Phase Diagram)

2019　Physical Chemistry (Phase Diagram)

Font size S M L

Academic unit or major: Undergraduate major in Materials Science and Engineering

Instructor(s): Shioya Masatoshi

Class Format: Lecture

Media-enhanced courses

Day/Period(Room No.): Mon3-4(S8-102)

Group: -

Course number: MAT.P205

Credits: 1

Academic year: 2019

Offered quarter: 4Q

Syllabus updated: 2019/3/18

Lecture notes updated: -

Language used: Japanese

Access Index

Syllabus

Course description and aims

The processing and control of the texture of materials are often performed by using the physicochemical phenomena such as the phase transition, mixing and phase separation.
This course explains these phenomena for single, binary and ternary systems based on the chemical potential.

Student learning outcomes

With this course, the students acquire the skills of the model analysis on the phase transition and the phase equilibrium.

Keywords

Physical chemistry
Phase equilibrium
Phase transition
Phase separation
Phase diagram
Osmotic pressure

Competencies that will be developed

✔ Specialist skills

Intercultural skills

Communication skills

Critical thinking skills

Practical and/or problem-solving skills

Class flow

The lecture uses materials uploaded to OCW-i. In every lesson, quick question is given to investigate the degree of understanding.

Course schedule/Required learning

	Course schedule	Required learning
Class 1	Collision frequency and pressure of gas molecules, equations of state for ideal and real gases	Complete exercises in the material of OCW-i on the collision frequency and pressure of gas molecules, and equations of state for ideal and real gases.
Class 2	van der Waals loop, physical basis of the Maxwell construction	Complete exercises in the material of OCW-i on the van der Waals loop and physical basis of the Maxwell construction.
Class 3	Phase transition and chemical potential	Complete exercises in the material of OCW-i on the phase transition and chemical potential.
Class 4	Gibbs energy of mixing, interaction parameter, solubility parameter	Complete exercises in the material of OCW-i on the Gibbs energy of mixing, interaction parameter, and solubility parameter.
Class 5	Phase equilibrium, process of phase separation	Complete exercises in the material of OCW-i on the phase equilibrium and process of phase separation.
Class 6	Tie line, spinodal line, binodal line	Complete exercises in the material of OCW-i on the tie line, spinodal line, and binodal line.
Class 7	Phase diagram of binary system	Complete exercises in the material of OCW-i on the phase diagram of binary system.
Class 8	Phase diagram of ternary system	Complete exercises in the material of OCW-i on the phase diagram of ternary system.

Textbook(s)

Physical chemistry by P. Atkins and J. D. Paula, Tokyo Kagakudojin

Reference books, course materials, etc.

Materials uploaded to OCW-i

Assessment criteria and methods

The skills of the model analysis on the phase transition and the phase equilibrium are assessed with written examination.

Related courses

MAT.P204 ： Physical Chemistry (Thermodynamics)

Prerequisites (i.e., required knowledge, skills, courses, etc.)

None required.

TOKYO INSTITUTE OF TECHNOLOGY