This course is to discuss the basic theory and application of thermodynamics, solution and phase diagram.
At the end of this course, students will be able to:
1) Explain the basic concept of thermodynamics.
2) Use thermodynamics.
3) Understand and apply phase diagram.
Thermodynamics, Free energy, Entropy, Enthalpy, Ellingham diagram, Solution. Phase diagram
|Intercultural skills||Communication skills||Specialist skills||Critical thinking skills||Practical and/or problem-solving skills|
Slides will be used for explaining the each subjects. Attendance is taken in every class.
|Course schedule||Required learning|
|Class 1||Introduction and thermal analysis and calorimetry||Explain TG-DTA and static calorimetry|
|Class 2||Thermodynamics: the First law||Study about First law, State function, Enthalpy, Temperature dependency.|
|Class 3||Thermodynamics: the second law and the Gibbs energy||Study about The second law, Entropy, Free energy, Maxwell equation.|
|Class 4||Statistical interpretation for entropy||Study about Statistical interpretation of entropy.|
|Class 5||Thermodynamics: the third law||Study about The third law.|
|Class 6||Relation between the thermodynamic properties and physical properties||Study about Richards’s rule, Trouton’s rule, Neumann-Kopp’s rule、Boron-Harber cycle|
|Class 7||Free energy of heterogeneous system||Study about Free energy of heterogeneous system、Free energy of reaction、Ellingham diagram.|
|Class 8||Achievement test||Ti examine as "feed-back"|
|Class 9||Treatment of Solution (I)||partial molar quantity, calculation of partial molar quantity, relations between thermodynamic quantities|
|Class 10||Treatment of Solution (II)||free energy of solution formation, ideal solution, Raoult's law, regular solution, Henry's law|
|Class 11||Application of quasichemical approach for solution (I)||quasichemical approach, attractive interaction, repulsive interaction|
|Class 12||Application of quasichemical approach for solution (II)||application of quasichemical approach for order-disorder reactions, long-range order parameter、short−range order parameter|
|Class 13||Understanding of binary phase diagram (I)||system, phase, equilibrium, Gibbs' phase rule, degree of freedom, single phase diagrambinary phase diagram|
|Class 14||Understanding of binary phase diagram (II)||binary phase diagram, eutectic point, lever rule, congruent melting compound, incongruent melting compound|
|Class 15||Free energy of binary systems||Free energy of binary systems|
R. A. Swalin. Thermodynamics of Solids. John Wiley & Sons, New York.
(Sakai) Course materials are provide during class.
(Shinozaki) All materials used in class can be found on OCW-i.
Student's course scores are based on midterm (Sakai:45%) and final (Shinozaki:45%) exams and attendance (10%).