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- Academic unit or major
- Inorganic Materials
- Instructor(s)
- Sakai Etsuo Shinozaki Kazuo
- Class Format
- Lecture
- Media-enhanced courses
- Day/Period(Room No.)
- Tue1-2(S7-201) Fri1-2(S7-201)
- Group
- -
- Course number
- ZUH.C202
- Credits
- 2
- Academic year
- 2016
- Offered quarter
- 1Q
- Syllabus updated
- 2016/4/27
- Lecture notes updated
- 2016/5/27
- Language used
- Japanese
- Access Index
-
Course description and aims
This course is to discuss the basic theory and application of thermodynamics, solution and phase diagram.
Student learning outcomes
At the end of this course, students will be able to:
1) Explain the basic concept of thermodynamics.
2) Use thermodynamics.
3) Understand and apply phase diagram.
Keywords
Thermodynamics, Free energy, Entropy, Enthalpy, Ellingham diagram, Solution. Phase diagram
Competencies that will be developed
| ✔ Specialist skills | Intercultural skills | Communication skills | Critical thinking skills | Practical and/or problem-solving skills |
Class flow
Slides will be used for explaining the each subjects. Attendance is taken in every class.
Course schedule/Required learning
| Course schedule | Required learning | |
|---|---|---|
| Class 1 | Introduction and thermal analysis and calorimetry | Explain TG-DTA and static calorimetry |
| Class 2 | Thermodynamics: the First law | Study about First law, State function, Enthalpy, Temperature dependency. |
| Class 3 | Thermodynamics: the second law and the Gibbs energy | Study about The second law, Entropy, Free energy, Maxwell equation. |
| Class 4 | Statistical interpretation for entropy | Study about Statistical interpretation of entropy. |
| Class 5 | Thermodynamics: the third law | Study about The third law. |
| Class 6 | Relation between the thermodynamic properties and physical properties | Study about Richards’s rule, Trouton’s rule, Neumann-Kopp’s rule、Boron-Harber cycle |
| Class 7 | Free energy of heterogeneous system | Study about Free energy of heterogeneous system、Free energy of reaction、Ellingham diagram. |
| Class 8 | Achievement test | Ti examine as "feed-back" |
| Class 9 | Treatment of Solution (I) | partial molar quantity, calculation of partial molar quantity, relations between thermodynamic quantities |
| Class 10 | Treatment of Solution (II) | free energy of solution formation, ideal solution, Raoult's law, regular solution, Henry's law |
| Class 11 | Application of quasichemical approach for solution (I) | quasichemical approach, attractive interaction, repulsive interaction |
| Class 12 | Application of quasichemical approach for solution (II) | application of quasichemical approach for order-disorder reactions, long-range order parameter、short−range order parameter |
| Class 13 | Understanding of binary phase diagram (I) | system, phase, equilibrium, Gibbs' phase rule, degree of freedom, single phase diagrambinary phase diagram |
| Class 14 | Understanding of binary phase diagram (II) | binary phase diagram, eutectic point, lever rule, congruent melting compound, incongruent melting compound |
| Class 15 | Free energy of binary systems | Free energy of binary systems |
Textbook(s)
R. A. Swalin. Thermodynamics of Solids. John Wiley & Sons, New York.
Reference books, course materials, etc.
(Sakai) Course materials are provide during class.
(Shinozaki) All materials used in class can be found on OCW-i.
Assessment criteria and methods
Student's course scores are based on midterm (Sakai:45%) and final (Shinozaki:45%) exams and attendance (10%).
Related courses
- None
Prerequisites (i.e., required knowledge, skills, courses, etc.)
No prerequisites.
