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- Liberal arts and basic science courses
- Academic unit or major
- Graduate major in Chemistry
- Instructor(s)
- Takaya Jun
- Class Format
- Lecture (Face-to-face)
- Media-enhanced courses
- Day/Period(Room No.)
- Mon3-4(W242) Thr3-4(W242)
- Group
- -
- Course number
- CHM.D433
- Credits
- 2
- Academic year
- 2022
- Offered quarter
- 3Q
- Syllabus updated
- 2022/4/20
- Lecture notes updated
- -
- Language used
- English
- Access Index
-
Course description and aims
Fundamental aspects of organometallic compounds will be described first, and then application to synthetic organic reactions using these organometallic compounds will be presented. Initially, synthesis and reaction of main group organometallic compounds will be discussed. Then fundamental aspects of transition metal complexes on structure, oxidation state and ligands will be discussed. Then basic reactions of transition metal compounds will be shown, and application to various kinds of synthetic reactions such as coupling reaction, metathesis reaction, etc. will be presented. Students can obtain basic knowledge of organic reactions mediated or catalyzed by organometallic complexes.
Student learning outcomes
By the end of this course, students will be able to acquire basic knowledge of organometallic chemistry with emphasis on the application to synthetic organic reactions.
Keywords
Organometallic compound, Organic syntheis,
Competencies that will be developed
| ✔ Specialist skills | Intercultural skills | Communication skills | Critical thinking skills | Practical and/or problem-solving skills |
Class flow
At the beginning of the class, students are given exercise problems related to the lecture given last time to solve.
Course schedule/Required learning
| Course schedule | Required learning | |
|---|---|---|
| Class 1 | Synthesis and reaction of organolithium and magnesium compounds | Exercise problems might be given in this class. |
| Class 2 | Synthesis and reaction of group 12 metal compounds | Exercise problems might be given in this class. |
| Class 3 | Synthesis and reaction of group 13 metal compounds | Exercise problems might be given in this class. |
| Class 4 | Synthesis and reaction of group 14 metal compounds | Exercise problems might be given in this class. |
| Class 5 | Fundamental aspect of organotransition metal complexes 1 (structure, oxidation state, ligand) | Exercise problems might be given in this class. |
| Class 6 | Fundamental aspect of organotransition metal complexes 2 (elementary reactions) | Exercise problems might be given in this class. |
| Class 7 | Reaction of alkene-coordinated transition metal complexes | Exercise problems might be given in this class. |
| Class 8 | Reaction of alkyne, diene, and arene-coordinated transition metal complexes | Exercise problems might be given in this class. |
| Class 9 | Reaction of allylmetal complexes | Exercise problems might be given in this class. |
| Class 10 | Reaction of organocopper complexes | Exercise problems might be given in this class. |
| Class 11 | Cross coupling reactions 1 | Exercise problems might be given in this class. |
| Class 12 | Cross coupling reactions 2 | Exercise problems might be given in this class. |
| Class 13 | Reaction of metal hydride complexes | Exercise problems might be given in this class. |
| Class 14 | Reaction of metal carbene complexes | Exercise problems might be given in this class. |
Out-of-Class Study Time (Preparation and Review)
To enhance effective learning, students are encouraged to spend approximately 100 minutes preparing for class and another 100 minutes reviewing class content afterwards (including assignments) for each class.
They should do so by referring to textbooks and other course material.
Textbook(s)
None
Reference books, course materials, etc.
Lecture material will be uploaded via OCWi.
Hartwig: Organotransition Metal Chemistry: From Bonding to Catalysis (Univ Science Books)
Assessment criteria and methods
Exercise problems, report, and final exam. Students' knowledge of organotransition metal chemistry along with its application to synthetic organic reactions, and their ability to apply them to problems will be assessed.
Related courses
- CHM.D401 ： Basic Concepts of Organic Chemistry I
- CHM.D402 ： Basic Concepts of Organic Chemistry II
Prerequisites (i.e., required knowledge, skills, courses, etc.)
Expected to have basic knowledge of organic chemistry.
