Science of organic crystal is emphasized. Outline of crystal structure analysis, inter-molecular interactions, propitiates and reaction of molecular crystals are explained. There are many kinds of organic crystal around us. Pick-up the concept how to analysis and understand the properties and structure of organic crystals. Other important concept of special properties of organic crystal is also explained. Actual examples of organic crystal are introduced to understand the concepts. Especially, crystalline state reaction which is a dynamic phenomena in crystal is picked-up.
Students will be able to understand intermolecular interactions and crystalline-state reaction from theory to actual examples.
Crystal structure, molecular structure, X-ray, Structure Analysis, X-ray diffraction, neutron diffraction.
|✔ Specialist skills||Intercultural skills||Communication skills||Critical thinking skills||Practical and/or problem-solving skills|
quiz at the end of lecture.
|Course schedule||Required learning|
|Class 1||Introduction of crystal chemistry||Understanding the outline of crystal chemistry|
|Class 2||Symmetry in crystal||Understanding of symmetry in crystal|
|Class 3||Crystal structure analysis||Understanding the outline of crystal structure analysis|
|Class 4||Ionic bond||Understanding the binding energy in ionic crystal|
|Class 5||van der Waals interaction||Understanding the binding energy in van der Waals crystal|
|Class 6||charge transfer type interaction||Understanding the binding energy in charge transfer interaction|
|Class 7||hydrogen bonding||Understanding the binding energy in hydrogen bonding|
|Class 8||Polymorphism and phase transition||Understanding polymorph and phase transition theory|
|Class 9||Crystal structure prediction||Understanding the CSP method|
|Class 10||Molecular motion in crystal||Understanding of molecular motion in crystal|
|Class 11||Organic solid-state reaction by solid-state grinding||Understanding of Organic solid-state reaction by solid-state grinding|
|Class 12||Organic crystalline state reaction||Understanding of crystalline state reaction by light irradiation or heating|
|Class 13||Reaction mechanism elucidation by neutron diffraction analysis||Understanding of proton transfer mechanism by neutron diffraction|
|Class 14||Analysis of reaction intermediate||Understanding how to analysis the intermediate species in crystal|
|Class 15||Total discussion||Total discussion of the lecture series|
Y. Ohasi "Crystal chemistry - basic to latest example -" (Shokabo)
Supplemental material may be distributed in the lecture
Term end exam and interterm exam.
Understanding of crystallography would be a help.