Applied Organometallic Chemistry

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Lecturer
Tanaka Masato 
Place
Thr1-2(G113)  
Credits
Lecture2  Exercise0  Experiment0
Code
95025
Syllabus updated
2010/9/20
Lecture notes updated
2010/9/20
Semester
Fall Semester

Outline of lecture

譛画ゥ滄キ遘サ驥大ア樣険菴薙↓縺、縺縺ヲシ梧ァ矩シ悟ョ牙ョ壽ァシ悟渕譛ャ逧縺ェ驟堺ス榊ュ撰シ碁ク蛹也噪莉伜刈繝サ驍蜈逧閼ア髮「繝サ謖ソ蜈・繝サ繝吶シ繧ソ閼ア髮「遲峨ョ蝓コ譛ャ蜿榊ソ懈ァ縺ィ縺昴l縺ォ蜿翫⊂縺咎堺ス榊ュ舌サ貅カ蟐堤ュ峨ョ蠖ケ蜑イ縺ォ縺、縺縺ヲ隗」隱ャ縺吶k縲ゅ∪縺滂シ檎浹豐ケ蛹門ュヲ蟾・讌ュ繧蛹サ阮ャ蜩∝粋謌舌↓縺翫>縺ヲ螳溽畑縺輔l縺ヲ縺繧玖ァヲ蟐偵励Ο繧サ繧ケ縺ョ莉」陦ィ逧縺ェ繧ゅョ縺ォ縺、縺縺ヲ縺昴ョ繝。繧ォ繝九ぜ繝縺翫h縺ウ遐皮ゥカ髢狗匱縺ョ迴セ迥カ繧定ァ」隱ャ縺吶k縲ゅ&繧峨↓シ梧怏讖滄大ア槫喧蜷育黄縺昴ョ繧ゅョ繧呈カイ譎カ繧蟆朱崕譚先侭遲峨ョ讖溯ス譚先侭縺ィ縺励※逕ィ縺繧医≧縺ィ縺吶k譛霑代ョ遐皮ゥカ縺ョ蜍募髄縺ォ縺、縺縺ヲ繧りァヲ繧後k縲

1.Introduction: History, application and research trends
2.General properties of transition metal organometallic complexes (竇): Electron counting, 18-electron rule, and oxidation state
3.General properties of transition metal organometallic complexes (竇。): Bonding, structure and coordination number
4.General properties of transition metal organometallic complexes (竇「): Classification and the nature of ligands and effect of complexation
5.Reactivity of transition metal organometallic compounds (竇): Oxidative addition and reductive elimination
6.Reactivity of transition metal organometallic compounds (竇。): Insertion reaction, direct attack to the ligand, and other reactivities
7.Homogeneous catalysis of practical importance (竇): Addition reactions such as hydroformylation, hydrosilylation, hydrocyanation and polymerization
8.Homogeneous catalysis of practical importance (竇。): Substituion reactions such as Wacker process, cross-coupling and Heck reaction
9.Recent research trends in homogeneous catalysis (竇): C-H and C-C bond activation
10.Recent research trends in homogeneous catalysis (竇。): Asymmetric catalysis
11.Main group metal organometallics
12.Inorganometallic chemistry
13.Organometallics in materials science (竇): Strucural metarials
14.Organometallics in materials science (竇。): Electronic, and optoelectronic applications

Purpose of lecture

譛画ゥ滄キ遘サ驥大ア樣険菴薙↓縺、縺縺ヲ縲∵ァ矩縲∝ョ牙ョ壽ァ縲∝渕譛ャ逧縺ェ驟堺ス榊ュ舌驟ク蛹也噪莉伜刈繝サ驍蜈逧閼ア髮「繝サ謖ソ蜈・繝サ繝吶シ繧ソ閼ア髮「遲峨ョ蝓コ譛ャ逧蜿榊ソ懊→縺昴l縺ォ蜿翫⊂縺咎堺ス榊ュ舌サ貅カ蟐堤ュ峨ョ蠖ケ蜑イ縺ォ縺、縺縺ヲ隗」隱ャ縺吶k縲ゅ&繧峨↓縲∵怏讖滄大ア槫喧蜷育黄縺昴ョ繧ゅョ繧呈カイ譎カ繧蟆朱崕菴捺攝譁咏ュ峨ョ讖溯ス譚先侭縺ィ縺励※逕ィ縺繧医≧縺ィ縺吶k譛霑代ョ遐皮ゥカ縺ョ蜍募髄縺ォ縺、縺縺ヲ繧りァヲ繧後k縲

Plan of lecture

1.Introduction: History, application and research trends
2.General properties of transition metal organometallic complexes (I) :Electron counting, 18-electron rule, and oxidation state
3.General properties of transition metal organometallic complexes (II) :Bonding, Structure and coordination number
4.General properties of transition metal organometallic complexes (III) :Classification and the nature of ligands and effect of complexation
5.Reactivity of transition metal organometallic compounds (I) :Oxidative addition and reductive elimination
6.Reactivity of transition metal organometallic compounds (II) :Insertion reaction, direct attack to the ligand, and other reactivities
7.Homogeneous catalysis of practical importance (I) :Addition reactions such as hydroformylation, hydrosilylation, hydrocyanation and polymerization
8.Homogeneous catalysis of practical importance (II) :Substituion reactions such as Wacker process, cross-coupling and Heck reaction
9.Recent research trends in homogeneous catalysis (I) :C-H and C-C bond activation
10.Recent research trends in homogeneous catalysis (II) :Asymetric catalysis
11.Main group metal organometallics
12.Inorganometallic chemistry
13.Organometallics in materials science (I) : Strucural metarials
14.Organometallics in materials science (II) : Electronic and optoelectronic applications

Textbook and reference

The Organometallic Chemistry of Transition Metals, Robert H. Crabtree, John Wiley & Sons

Related and/or prerequisite courses

Basic knowledge of organic chemistry is essential.

Evaluation

Based on a report on a recent publication, which will be assigned individually.

Comments from lecturer

Japanese students are also encouraged to join, but everything will be given in English.

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