講義概要
有機電極プロセスはファインケミカルズや機能性材料の合成のための極めて有用な方法である。本講義では，下記のトピックスを網羅する。
１）有機電極プロセスの基礎
２）ファインケミカルズ合成への応用
３）導電性高分子合成への応用
４）有機電極プロセスの新しい展開
Organic electrode process is of much importance in order to prepare various fine chemicals and functional materials.
This lecture will cover the following topics.
1.Introduction
2.History of organic electrode process, Fundamental aspects of organic electrode processes (1)
3.Fundamental aspects of organic electrode processes (2)
4.Methods for studies of organic electrode processes (1)
5.Methods for studies of organic electrode processes (2)
6.Mechanistic aspects of organic electrode processes (Electrogenerated reactive species: Properties and synthetic utilizations)
7.Synthetic aspects of organic electrode processes (Adsorption mechanism and stereo- and regioselective reactions)
8.Synthetic aspects of organic electrode processes (Hydrocarbons, Heteroatom-containing compounds, Heterocyclic compounds)
9.Synthetic aspects of organic electrode processes (Organometallic compounds, Organofluoro compounds)
10.New trends of organic electrode processes (Electrogenerated acids and bases: Mediatory reactions)
11.New trends of organic electrode processes (Concepts and applications of modified electrodes)
12.New trends of organic electrode processes (C1-chemistry, Biomass, Asymmetric synthesis)
13.New trends of organic electrode processes (Paired electrosynthesis, Photoelectrolysis, Electropolimerization, SPE electrolysis)
14.Application to industrial processes
講義の目的
Organic electrode process is of much importance in order to prepare various fine chemicals and functional materials.
講義計画
1.Introduction
2.History of organic electrode process, Fundamental aspects of organic electrode process (1)
3.Fundamental aspects of organic electrode processes (2)
4.Methods for studies of organic electrode processes (1)
5.Methods for studies of organic electrode processes (2)
6.Mechanistic aspects of organic electrode processes (Electrogenerated reactive species: Properties and synthetic utilizations)
7.Synthetic aspects of organic electrode processes (Adsorption mechanism and stereo- and regioselective reactions)
8.Synthetic aspects of organic electrode processes (Hydrocarbons, Heteroatom-containing compounds, Heterocyclic compounds)
9.Synthetic aspects of organic electrode processes (Organometallic compounds, Organofluoro compounds)
10.New trends of organic electrode processes (Electrogenerated acids and bases: Mediatory reactions)
11.New trends of organic electrode processes (Concepts and applications of modified electrodes)
12.New trends of organic electrode processes (C1-chemistry, Biomass, Asymmetric synthesis)
13.New trends of organic electrode processes (Paired electrosynthesis, Photoelectrolysis, Electropolimerization, SPE electrolysis)
14.Application of electrode potentials (2)
教科書・参考書等
Organic Electrochemistry (Ed. by H. Lund and O. Hammerich , Dekker, New York, 2001)
成績評価
Attendance and Examination
