- Lecturer
- Tanaka Masato
- Place
- Thr1-2(G113)
- Credits
- Lecture2 Exercise0 Experiment0
- Code
- 95025
- Syllabus updated
- 2008/10/1
- Lecture notes updated
- 2008/10/1
- Semester
- Fall Semester
Outline of lecture
譛画ｩ滄ｷ遘ｻ驥大ｱ樣険菴薙↓縺､縺縺ｦｼ梧ｧ矩ｼ悟ｮ牙ｮ壽ｧｼ悟渕譛ｬ逧縺ｪ驟堺ｽ榊ｭ撰ｼ碁ｸ蛹也噪莉伜刈繝ｻ驍蜈逧閼ｱ髮｢繝ｻ謖ｿ蜈･繝ｻ繝吶ｼ繧ｿ閼ｱ髮｢遲峨ｮ蝓ｺ譛ｬ蜿榊ｿ懈ｧ縺ｨ縺昴ｌ縺ｫ蜿翫⊂縺咎堺ｽ榊ｭ舌ｻ貅ｶ蟐堤ｭ峨ｮ蠖ｹ蜑ｲ縺ｫ縺､縺縺ｦ隗｣隱ｬ縺吶ｋ縲ゅ∪縺滂ｼ檎浹豐ｹ蛹門ｭｦ蟾･讌ｭ繧蛹ｻ阮ｬ蜩∝粋謌舌↓縺翫＞縺ｦ螳溽畑縺輔ｌ縺ｦ縺繧玖ｧｦ蟐偵励Ο繧ｻ繧ｹ縺ｮ莉｣陦ｨ逧縺ｪ繧ゅｮ縺ｫ縺､縺縺ｦ縺昴ｮ繝｡繧ｫ繝九ぜ繝縺翫ｈ縺ｳ遐皮ｩｶ髢狗匱縺ｮ迴ｾ迥ｶ繧定ｧ｣隱ｬ縺吶ｋ縲ゅ＆繧峨↓ｼ梧怏讖滄大ｱ槫喧蜷育黄縺昴ｮ繧ゅｮ繧呈ｶｲ譎ｶ繧蟆朱崕譚先侭遲峨ｮ讖溯ｽ譚先侭縺ｨ縺励※逕ｨ縺繧医≧縺ｨ縺吶ｋ譛霑代ｮ遐皮ｩｶ縺ｮ蜍募髄縺ｫ縺､縺縺ｦ繧りｧｦ繧後ｋ縲
1.Introduction: History, application and research trends
2.General properties of transition metal organometallic complexes (竇): Electron counting, 18-electron rule, and oxidation state
3.General properties of transition metal organometallic complexes (竇｡): Bonding, structure and coordination number
4.General properties of transition metal organometallic complexes (竇｢): Classification and the nature of ligands and effect of complexation
5.Reactivity of transition metal organometallic compounds (竇): Oxidative addition and reductive elimination
6.Reactivity of transition metal organometallic compounds (竇｡): Insertion reaction, direct attack to the ligand, and other reactivities
7.Homogeneous catalysis of practical importance (竇): Addition reactions such as hydroformylation, hydrosilylation, hydrocyanation and polymerization
8.Homogeneous catalysis of practical importance (竇｡): Substituion reactions such as Wacker process, cross-coupling and Heck reaction
9.Recent research trends in homogeneous catalysis (竇): C-H and C-C bond activation
10.Recent research trends in homogeneous catalysis (竇｡): Asymmetric catalysis
11.Main group metal organometallics
12.Inorganometallic chemistry
13.Organometallics in materials science (竇): Strucural metarials
14.Organometallics in materials science (竇｡): Electronic, and optoelectronic applications
Purpose of lecture
譛画ｩ滄ｷ遘ｻ驥大ｱ樣険菴薙↓縺､縺縺ｦ縲∵ｧ矩縲∝ｮ牙ｮ壽ｧ縲∝渕譛ｬ逧縺ｪ驟堺ｽ榊ｭ舌驟ｸ蛹也噪莉伜刈繝ｻ驍蜈逧閼ｱ髮｢繝ｻ謖ｿ蜈･繝ｻ繝吶ｼ繧ｿ閼ｱ髮｢遲峨ｮ蝓ｺ譛ｬ逧蜿榊ｿ懊→縺昴ｌ縺ｫ蜿翫⊂縺咎堺ｽ榊ｭ舌ｻ貅ｶ蟐堤ｭ峨ｮ蠖ｹ蜑ｲ縺ｫ縺､縺縺ｦ隗｣隱ｬ縺吶ｋ縲ゅ＆繧峨↓縲∵怏讖滄大ｱ槫喧蜷育黄縺昴ｮ繧ゅｮ繧呈ｶｲ譎ｶ繧蟆朱崕菴捺攝譁咏ｭ峨ｮ讖溯ｽ譚先侭縺ｨ縺励※逕ｨ縺繧医≧縺ｨ縺吶ｋ譛霑代ｮ遐皮ｩｶ縺ｮ蜍募髄縺ｫ縺､縺縺ｦ繧りｧｦ繧後ｋ縲
Plan of lecture
1.Introduction: History, application and research trends
2.General properties of transition metal organometallic complexes (I) :Electron counting, 18-electron rule, and oxidation state
3.General properties of transition metal organometallic complexes (II) :Bonding, Structure and coordination number
4.General properties of transition metal organometallic complexes (III) :Classification and the nature of ligands and effect of complexation
5.Reactivity of transition metal organometallic compounds (I) :Oxidative addition and reductive elimination
6.Reactivity of transition metal organometallic compounds (II) :Insertion reaction, direct attack to the ligand, and other reactivities
7.Homogeneous catalysis of practical importance (I) :Addition reactions such as hydroformylation, hydrosilylation, hydrocyanation and polymerization
8.Homogeneous catalysis of practical importance (II) :Substituion reactions such as Wacker process, cross-coupling and Heck reaction
9.Recent research trends in homogeneous catalysis (I) :C-H and C-C bond activation
10.Recent research trends in homogeneous catalysis (II) :Asymetric catalysis
11.Main group metal organometallics
12.Inorganometallic chemistry
13.Organometallics in materials science (I) : Strucural metarials
14.Organometallics in materials science (II) : Electronic and optoelectronic applications
