- Lecturer
- Susa Masahiro
- Place
- Tue5-6(S8-501)
- Credits
- Lecture2 Exercise0 Experiment0
- Code
- 24006
- Syllabus updated
- 2008/10/1
- Lecture notes updated
- 2008/10/1
- Semester
- Fall Semester
Outline of lecture
譚先侭縺ｯｼ瑚檮菴薙ｒ邨檎罰縺励※陬ｽ騾縺輔ｌ繧九％縺ｨ縺悟､壹＞縲ゅ＠縺溘′縺｣縺ｦｼ後◎縺ｮ迚ｩ逅蛹門ｭｦ逧諤ｧ雉ｪ繧堤炊隗｣縺吶ｋ縺薙→縺ｯｼ梧攝譁吶励Ο繧ｻ繧ｹ縺ｮ險ｭ險医♀繧医ｳ縺昴ｮ譛驕ｩ蛹悶ｒ蝗ｳ繧九◆繧√↓縺ｯ荳榊庄谺縺ｧ縺ゅｋ縲よ悽隰帷ｾｩ縺ｧ縺ｯｼ碁大ｱ槭♀繧医ｳ驟ｸ蛹也黄陞堺ｽ薙ｮ辭ｱ蜉帛ｭｦ縺翫ｈ縺ｳ迥ｶ諷句峙繧定ｻｸ縺ｨ縺励※ｼ梧ｴｻ驥上ｮ菴ｿ縺譁ｹ繧迥ｶ諷句峙ｼ後→縺上↓陞堺ｽ薙ｒ蜷ｫ繧荳牙邉ｻ縺ｮ迥ｶ諷句峙縺ｮ隱ｭ縺ｿ譁ｹ繧堤ｿ貞ｾ励☆繧九％縺ｨ繧堤岼逧縺ｨ縺吶ｋ縲よｼ皮ｿ偵ｂ螟壽焚陦後≧縲
Many materials are produced via the state of melts and thus understanding of physico-chemica
Purpose of lecture
The term of 'melts' essentially means what the term of 'liquid' does and is often used, in particular, when one refers to the state of substances which are melted at high temperatures. In this usage, for example, liquid iron is a kind of melt but liquid water is not. Many materials are produced via the state of melts and thus understanding of physico-chemical properties of melts is essential to materials process designing and its optimisation. This lecture mainly centres upon thermodynamics and phase diagrams for metal and its oxide melts, and aims at learning how to use the activity and how to read phase diagrams, in particular, for ternary systems containing melts, through many exercises.
Plan of lecture
01.Basic Thermodynamics [Ellingham diagram 1]
02.Basic Thermodynamics [Ellingham diagram 2, for CO/CO2 scale and solute metals]
03.Activity [Law of mass action and concept of activity]
04.Activity [Raoultian and Henrian standard activities]
05.Activity [Henrian activities by mole fraction and mass% expressions]
06.Activity [Interaction parameters]
07.Phase diagram for binary system [Lever rule, and eutectic and peritectic systems]
08.Phase diagram for ternary system [Method of determining composition]
09.Phase diagram for ternary system [Isoplethal studies in systems containing eutectic reactions]
10.Phase diagram for ternary system [Alkemade lines and composition triangles]
11.Phase diagram for ternary system [Isothermal sections]
12.Phase diagram for ternary system [Isoplethal studies in systems containing peritectic reactions]
Textbook and reference
01.Japan Institute of Metals: Physical Chemistry of Metals (in Japanese)
02.D. R. Gaskell: Introduction to the Thermodynamics of Materials, Taylor & Francis
03.C. G. Bergeron and S. H. Risbud: Introduction to Phase Equilibria in Ceramics, The American Ceramic Society
Related and/or prerequisite courses
Nothing particular
Evaluation
Attendance, submission of assignments and final exam
Comments from lecturer
Students who can take the course are limited only to those who want to learn
Supplement
縲先ｦりｦ√
譚先侭縺ｯｼ瑚檮菴薙ｒ邨檎罰縺励※陬ｽ騾縺輔ｌ繧九％縺ｨ縺悟､壹＞縲ゅ＠縺溘′縺｣縺ｦｼ後◎縺ｮ迚ｩ逅蛹門ｭｦ逧諤ｧ雉ｪ繧堤炊隗｣縺吶ｋ縺薙→縺ｯｼ梧攝譁吶励Ο繧ｻ繧ｹ縺ｮ險ｭ險医♀繧医ｳ縺昴ｮ譛驕ｩ蛹悶ｒ蝗ｳ繧九◆繧√↓縺ｯ荳榊庄谺縺ｧ縺ゅｋ縲よ悽隰帷ｾｩ縺ｧ縺ｯｼ碁大ｱ槭♀繧医ｳ驟ｸ蛹也黄陞堺ｽ薙ｮ辭ｱ蜉帛ｭｦ縺翫ｈ縺ｳ迥ｶ諷句峙繧定ｻｸ縺ｨ縺励※ｼ梧ｴｻ驥上ｮ菴ｿ縺譁ｹ繧迥ｶ諷句峙ｼ後→縺上↓陞堺ｽ薙ｒ蜷ｫ繧荳牙邉ｻ縺ｮ迥ｶ諷句峙縺ｮ隱ｭ縺ｿ譁ｹ繧堤ｿ貞ｾ励☆繧九％縺ｨ繧堤岼逧縺ｨ縺吶ｋ縲よｼ皮ｿ偵ｂ螟壽焚陦後≧縲
縲植bstract縲
Many materials are produced via the state of melts and thus understanding of physico-chemical properties of melts is essential to materials process designing and its optimisation. This lecture mainly centres upon thermodynamics and phase diagrams for metal and its oxide melts, and aims at learning how to use the activity and how to read phase diagrams, in particular, for ternary systems containing melts, through many exercises.
